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You can run the a Power Shell script similar to following example to dump items in the list and get an idea of the other user properties stored in this list.
I’ve tested this in my own lab by changing the Department and Title properties for a user account in AD and then forcing a Full sync in Share Point, and it appeared to work as expected.
The user property changes were replicated from AD into the user profile, the userinfo table, and into the hidden User Information List in the site collection.
Important: If you plan to delete the user from the All People group, all the user's permissions to this Site Collection are removed.
To do this from the Share Point site collection, you can go to Site Actions In Microsoft Office Share Point 2007, you could remove the user from the All People group and re-add them.
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